Proceedings of the 4th 2016 International Conference on Material Science and Engineering (ICMSE 2016)

Catalytic Oxidation Desulfurization over PTA-dispersed MIL-101 under Mild Conditions

Authors
Yong Liu, Jian-Fei Bai, Xiao-Hong Yin, Hong-Tao Duan, Yan-Fei Zhang
Corresponding Author
Yong Liu
Available Online December 2016.
DOI
10.2991/icmse-16.2016.1How to use a DOI?
Keywords
Oxidation desulfurization, Dibenzothiophene (DBT), Metal-organic frameworks, Phosphotungstic acid (PTA), Aromatics
Abstract

With H2O2 as oxidant, phosphotungstic acid (PTA) was used as heterogeneous oxidation desulfurization catalyst via immobilizing on porous MIL-101. By combining the catalytic activity of PTA with the adsorption property of supporter MIL-101, 91.2% of dibenzothiophene (DBT) in model fuel has been removed. Even with benzene and p-xylene co-existed, 0.5PTA/MIL remained its activity in catalytic oxidation of DBT. However, when TBHP was used as an alternative of H2O2 in this reaction system, no conversion of dibenzothiophene (DBT) was detected.

Copyright
© 2016, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 4th 2016 International Conference on Material Science and Engineering (ICMSE 2016)
Series
Advances in Engineering Research
Publication Date
December 2016
ISBN
10.2991/icmse-16.2016.1
ISSN
2352-5401
DOI
10.2991/icmse-16.2016.1How to use a DOI?
Copyright
© 2016, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Yong Liu
AU  - Jian-Fei Bai
AU  - Xiao-Hong Yin
AU  - Hong-Tao Duan
AU  - Yan-Fei Zhang
PY  - 2016/12
DA  - 2016/12
TI  - Catalytic Oxidation Desulfurization over PTA-dispersed MIL-101 under Mild Conditions
BT  - Proceedings of the 4th 2016 International Conference on Material Science and Engineering (ICMSE 2016)
PB  - Atlantis Press
SP  - 1
EP  - 7
SN  - 2352-5401
UR  - https://doi.org/10.2991/icmse-16.2016.1
DO  - 10.2991/icmse-16.2016.1
ID  - Liu2016/12
ER  -