Proceedings of the 2015 4th International Conference on Sensors, Measurement and Intelligent Materials

Phenol hydrogenation over Pd/ZrO2 using ethanol as hydrogen source

Authors
Yunjie Shi, Bin Wang, Junjun Shen, Rongrong Miao
Corresponding Author
Yunjie Shi
Available Online January 2016.
DOI
https://doi.org/10.2991/icsmim-15.2016.140How to use a DOI?
Keywords
Ethanol, Phenol, Hydrogenation, Pd/ZrO2
Abstract

Phenol hydrogenation over the Pd/ZrO2 catalyst has been carried out using ethanol as hydrogen source. The reaction temperature, catalyst and ethanol quantity are found to be influencing factors for effective phenol conversion. In all cases, low quantity (5%~10%) of ethanol and high temperature is efficient for a high phenol conversion. The results show that low quantity (5%~10%) of ethanol is efficient for high cyclohexanone selectivity at low temperature (573K). However, the selectivity of cyclohexanone, cyclohexanol and cyclohexane are insensitive to the ethanol quantity at high temperature (653K). It seems that ethanol plays an important dual role: as hydrogen source and as additive to control the phenol conversion and products selectivity.

Copyright
© 2016, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2015 4th International Conference on Sensors, Measurement and Intelligent Materials
Series
Advances in Computer Science Research
Publication Date
January 2016
ISBN
978-94-6252-157-5
ISSN
2352-538X
DOI
https://doi.org/10.2991/icsmim-15.2016.140How to use a DOI?
Copyright
© 2016, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Yunjie Shi
AU  - Bin Wang
AU  - Junjun Shen
AU  - Rongrong Miao
PY  - 2016/01
DA  - 2016/01
TI  - Phenol hydrogenation over Pd/ZrO2 using ethanol as hydrogen source
BT  - Proceedings of the 2015 4th International Conference on Sensors, Measurement and Intelligent Materials
PB  - Atlantis Press
SP  - 745
EP  - 749
SN  - 2352-538X
UR  - https://doi.org/10.2991/icsmim-15.2016.140
DO  - https://doi.org/10.2991/icsmim-15.2016.140
ID  - Shi2016/01
ER  -