Proceedings of the 1st Nusa Tenggara International Conference on Chemistry (NITRIC 2022)

Kinetics of Gas and Liquid Smoke from Catalytic Pyrolysis of Human Hair Cut Waste and Its Characterization

Authors
I Dewe K. Anom1, *, Marianus2, J. Z. Lombok1, Lalu Rudyat Telly Savalas3
1Department of Chemistry, Faculty of Mathematics and Natural Science, Manado State University, Jl. Raya Tondano, Koya, Regency Minahasa, Tondano, North Sulawesi, Indonesia
2Department of Physics, Faculty of Mathematics and Natural Science, Manado State University, Jl. Raya Tondano, Koya, Regency Minahasa, Tondano, North Sulawesi, Indonesia
3Chemistry Education Study Program, University of Mataram, Jl. Majapahit No. 62, Mataram, West Nusa Tenggara, Indonesia
*Corresponding author. Email: dewaanom10@gmail.com
Corresponding Author
I Dewe K. Anom
Available Online 14 April 2023.
DOI
10.2991/978-94-6463-130-2_8How to use a DOI?
Keywords
Kinetics; gas; liquid smoke; pyrolysis; catalytic; hair; characterization
Abstract

Human haircut waste (HHW) is categorized as waste that is difficult to decompose by microorganisms in water and soil and has high stability to temperature. HHW disposal carelessly will cause environmental pollution problems. Incineration of HHW produces gas with a pungent odor that can interfere with the health of humans and other living organisms. Therefore, there is a need for a solution to handle HHW to prevent environmental pollution. The main objective of this research is to study the reaction kinetics of gas and liquid smoke formation resulting from the catalytic pyrolysis of HHW and its characterization. Pyrolysis is the method used in this study. The catalytic pyrolysis of HHW resulting in the gas and liquid smoke formation follows a first-order reaction, with the R-value for gas and liquid smoke being R2 = 0.9609 and 0.9652, respectively. The relationship between the constant value of the reaction rate for the formation of gaseous products and temperature can be expressed in the Arrhenius equation k = Ae−2,985.2/T with an activation energy value (Ea) of 24.818 × 103 kJ/mol, while the liquid smoke is expressed in the Arrhenius equation k = Ae−1.297.5/T with an Ea of 10.787 × 103 kJ/mol. The characteristics of physical properties of liquid smoke from HHW are not yet suitable for use as fuel oil. Thereby, a method for further purification is needed so that the products can be used as fuel or other chemicals. Liquid smoke resulting from HHW pyrolysis is a mixture of 30 chemical compounds, and some of them are unstable compounds which could be indicated by a change in the color of the liquid smoke from pale yellow to dark brown in a relatively short time. Therefore, HHW liquid smoke must be stabilized with chemical stabilizers for long-term storage.

Copyright
© 2023 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

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Volume Title
Proceedings of the 1st Nusa Tenggara International Conference on Chemistry (NITRIC 2022)
Series
Atlantis Highlights in Chemistry and Pharmaceutical Sciences
Publication Date
14 April 2023
ISBN
10.2991/978-94-6463-130-2_8
ISSN
2590-3195
DOI
10.2991/978-94-6463-130-2_8How to use a DOI?
Copyright
© 2023 The Author(s)
Open Access
Open Access This chapter is licensed under the terms of the Creative Commons Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/), which permits any noncommercial use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license and indicate if changes were made.

Cite this article

TY  - CONF
AU  - I Dewe K. Anom
AU  - Marianus
AU  - J. Z. Lombok
AU  - Lalu Rudyat Telly Savalas
PY  - 2023
DA  - 2023/04/14
TI  - Kinetics of Gas and Liquid Smoke from Catalytic Pyrolysis of Human Hair Cut Waste and Its Characterization
BT  - Proceedings of the 1st Nusa Tenggara International Conference on Chemistry (NITRIC 2022)
PB  - Atlantis Press
SP  - 60
EP  - 74
SN  - 2590-3195
UR  - https://doi.org/10.2991/978-94-6463-130-2_8
DO  - 10.2991/978-94-6463-130-2_8
ID  - Anom2023
ER  -