Mn-, Ru-Coordinated Covalent Triazine Framework as Catalysts for Epoxidation of Cyclohexene
- DOI
- 10.2991/ap3er-15.2015.26How to use a DOI?
- Keywords
- Covalent triazine framework; polymerization; cyclohexene epoxidation; catalysis; coordination
- Abstract
The alkene epoxidation is an important reaction for organic synthesis and the catalytic epoxidation of cyclohexene can be widely used for the synthesis of fine chemicals. In this work, a new kind of heterogeneous catalysts, Mn/Ru coorindated covalent triazine framework (Mn-CTF and Ru-CTF), for oxidation of cyclohexene to epoxy hexane were designed. The catalyst Mn-CTF/Ru-CTF was prepared via coordination of manganese chloride hydrate/ruthenium trichloride (III) hydrate with CTF, which was obtained by self-polymerization of 2, 6-pyridinedicarbonitrile. Reducing and oxidizing agents are isobutyraldehyde and molecular oxygen. The yield of epoxidation reaction of cyclohexene catalyzed by the Mn-CTF and Ru-CTF can be up to 97% and 99% under room temperature and atmospheric pressure, respectively.
- Copyright
- © 2015, the Authors. Published by Atlantis Press.
- Open Access
- This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Cite this article
TY - CONF AU - Xue Liu AU - Ling Zhang AU - Wei-Qiao Deng AU - Nian-Yu Huang PY - 2015/06 DA - 2015/06 TI - Mn-, Ru-Coordinated Covalent Triazine Framework as Catalysts for Epoxidation of Cyclohexene BT - Proceedings of the 2015 Asia-Pacific Energy Equipment Engineering Research Conference PB - Atlantis Press SP - 107 EP - 110 SN - 2352-5401 UR - https://doi.org/10.2991/ap3er-15.2015.26 DO - 10.2991/ap3er-15.2015.26 ID - Liu2015/06 ER -