Proceedings of the 2017 6th International Conference on Energy and Environmental Protection (ICEEP 2017)

The effect of sintering temperature on the performance of IT-SOFC SrFe0.9Sb0.1O3- perovskite oxide

Authors
Xiuling Yu, Xue Li
Corresponding Author
Xiuling Yu
Available Online June 2017.
DOI
10.2991/iceep-17.2017.203How to use a DOI?
Keywords
Perovskite oxide; Electrical conductivity; Cathode; Polarization resistances; Sintering temperature
Abstract

The perovskite cathode material of SrFe0.9Sb0.1O3- (SFS) was prepared by glycine-nitrate process (GNP). The SFS oxides sintered at 1150,1200 and 1250 §C for 10 h were crystallized into a single phase perovskite structure, respectively. The effect of sintering temperature on crystal structure, conductivity and polarization resistance was also discussed in detail. The X-ray diffraction and SEM results show that the density increases with the increase of sintering temperature. The results of electrical properties show that the conductivity of SFS samples is dominated by p-type conductivity, and the conduction behavior is in accordance with the mechanism of small polaron jumping. With the rising sintering temperature, the conductivity of prepared samples increases gradually. In the temperature 650 800 §C, the conductivity values are 57.8 32.5, 63.6 35.8 and 74.5 40.3 S cm1 for the SFS samples of sintering at 1150, 1200 and 1250 §C, respectively. The SFS cathode has a good chemical compatibility with the SDC electrolyte at temperatures below 950 øC. The polarization resistances of SFS cathode were 0.064, 0.052 and 0.047 cm2 at 800 §C, respectively. The results show that the SFS material of sintering at 1250 øC has promising prospects for the application of IT-SOFCs.

Copyright
© 2017, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2017 6th International Conference on Energy and Environmental Protection (ICEEP 2017)
Series
Advances in Engineering Research
Publication Date
June 2017
ISBN
10.2991/iceep-17.2017.203
ISSN
2352-5401
DOI
10.2991/iceep-17.2017.203How to use a DOI?
Copyright
© 2017, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Xiuling Yu
AU  - Xue Li
PY  - 2017/06
DA  - 2017/06
TI  - The effect of sintering temperature on the performance of IT-SOFC SrFe0.9Sb0.1O3- perovskite oxide
BT  - Proceedings of the 2017 6th International Conference on Energy and Environmental Protection (ICEEP 2017)
PB  - Atlantis Press
SP  - 1162
EP  - 1168
SN  - 2352-5401
UR  - https://doi.org/10.2991/iceep-17.2017.203
DO  - 10.2991/iceep-17.2017.203
ID  - Yu2017/06
ER  -