Anion conducting chitosan/poly[(3-methyl-1-vinylimidazolium methyl sulfate)-co-(1-vinylcaprolactam)-co-(1-vinylpyrrolidone)] membrane for alkaline anion-exchange membrane fuel cells
Bei Ao, Yanan Wei, Xiaofan Hou, Keryn Lian, Jinli Qiao
Available Online April 2017.
- https://doi.org/10.2991/iceesd-17.2017.170How to use a DOI?
- Anion-exchange membrane, fuel cell, cross-linking, ionic conductivity, water uptake, oxidation stability.
- Anion-exchange membrane composed of chitosan (CS) and poly[(3-methyl-1-vinylimidazolium methyl sulfate)-co-(1-vinylcaprolactam)-co-(1- vinylpyrrolidone)] (PMVMS-co-VC-co-VP) was prepared by applying double cross-linking technique for alkaline membrane fuel cell (AMFC). Having tested the ion conductivity and water uptake without thermal cross-linking, the CS/PMVMS-co-VC-co-VP-OH- membrane (1:0.75 by mass) shows the ionic conductivity of 1.39 ž 10-3 S cm-1 with high water uptake of 88.45%. However, when the membrane was double cross-linked by both thermal and chemical cross-linking, the ionic conductivity of the membrane was improved and reached to 1.58ž10-3 S cm-1, instead, the water uptake of the membrane was largely decreased to lower than 48.02%. The oxidation stability of the membrane was also enhanced greatly. Moreover, the ionic conductivity increases as the temperature increased; with the maximum OH- conductivity of 3.85ž10-3 S cm-1 was obtained at 80oC.
- Open Access
- This is an open access article distributed under the CC BY-NC license.
Cite this article
TY - CONF AU - Bei Ao AU - Yanan Wei AU - Xiaofan Hou AU - Keryn Lian AU - Jinli Qiao PY - 2017/04 DA - 2017/04 TI - Anion conducting chitosan/poly[(3-methyl-1-vinylimidazolium methyl sulfate)-co-(1-vinylcaprolactam)-co-(1-vinylpyrrolidone)] membrane for alkaline anion-exchange membrane fuel cells BT - 2017 6th International Conference on Energy, Environment and Sustainable Development (ICEESD 2017) PB - Atlantis Press SP - 930 EP - 934 SN - 2352-5401 UR - https://doi.org/10.2991/iceesd-17.2017.170 DO - https://doi.org/10.2991/iceesd-17.2017.170 ID - Ao2017/04 ER -