Proceedings of the 3rd International Conference on Material Engineering and Application (ICMEA 2016)

Synthesis of Cyclohexanone Pentaerythritol Ketal Catalyzed by Sulfonated Zeolite

Authors
Jing-Fang XU, Jian-Long DONG, Qiang DENG, Xue-Fan GU, Ying TANG, Zhi-Fang ZHANG
Corresponding Author
Jing-Fang XU
Available Online December 2016.
DOI
10.2991/icmea-16.2016.48How to use a DOI?
Keywords
Cyclohexanone Pentaerythritol Ketal, X-Ray Structure, Thermal Character.
Abstract

In the previous research, it has been found that cyclohexanone pentaerythritol ketal has some bioactivity in the treatment of hurt in sports. In this work, cyclohexanone pentaerythritol ketal was synthesized from cyclohexanone and pentaerythritol by condensation catalyzed by zeolite and modified zeolite, and the reaction condition was discussed. It was characterized by NMR, MS spectrum and single-crystal X-ray diffraction. It crystallizes in orthorhombic space group, P21, with a unit cell dimensions of a = 11.1214(9) , b = 13.9216(6)  and c = 11.6658(10) . There are two molecules with different conformation in the crystal, varying from bond lengths to angles. The stacking interaction is responsible for the crystal's 1-D supra-molecular structure.

Copyright
© 2016, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 3rd International Conference on Material Engineering and Application (ICMEA 2016)
Series
Advances in Engineering Research
Publication Date
December 2016
ISBN
978-94-6252-272-5
ISSN
2352-5401
DOI
10.2991/icmea-16.2016.48How to use a DOI?
Copyright
© 2016, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Jing-Fang XU
AU  - Jian-Long DONG
AU  - Qiang DENG
AU  - Xue-Fan GU
AU  - Ying TANG
AU  - Zhi-Fang ZHANG
PY  - 2016/12
DA  - 2016/12
TI  - Synthesis of Cyclohexanone Pentaerythritol Ketal Catalyzed by Sulfonated Zeolite
BT  - Proceedings of the 3rd International Conference on Material Engineering and Application (ICMEA 2016)
PB  - Atlantis Press
SP  - 292
EP  - 296
SN  - 2352-5401
UR  - https://doi.org/10.2991/icmea-16.2016.48
DO  - 10.2991/icmea-16.2016.48
ID  - XU2016/12
ER  -