Proceedings of the 2015 International Conference on Materials, Environmental and Biological Engineering

The effect of boron incorporation on the thermo-oxidative stability of phenol-formaldehyde resin and its pyrolyzate phase

Authors
Jie Ding, Zhixiong Huang, Yan Qin, Haitao Luo, Jiawei Mao
Corresponding Author
Jie Ding
Available Online April 2015.
DOI
https://doi.org/10.2991/mebe-15.2015.234How to use a DOI?
Keywords
phenol-formaldehyde resin; boron; modified; thermo-oxidative stability; pyrolyzate
Abstract

The thermo-oxidative degradation behavior of the B-PF was studied using thermal gravimetry analysis (TGA-DTG) method. Compared with the unmodified resin (PF), the temperature at the maximum decomposing rate of the B-PF resin increases by 54 and its oxidative residues yield at 1000 enhances by 17.99 percent. The pyrolyzate of B-PF were further analyzed by XPS and XRD analysis. The analysis indicates that the boron element reacts with the air or oxygen-containing volatiles to generate boron nitride and boron oxide at elevated temperatures. In addition, incorporating boron into the carbon lattice increases the crystallite height and decreases the interlayer spacing.

Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2015 International Conference on Materials, Environmental and Biological Engineering
Series
Advances in Engineering Research
Publication Date
April 2015
ISBN
978-94-62520-57-8
ISSN
2352-5401
DOI
https://doi.org/10.2991/mebe-15.2015.234How to use a DOI?
Copyright
© 2015, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Jie Ding
AU  - Zhixiong Huang
AU  - Yan Qin
AU  - Haitao Luo
AU  - Jiawei Mao
PY  - 2015/04
DA  - 2015/04
TI  - The effect of boron incorporation on the thermo-oxidative stability of phenol-formaldehyde resin and its pyrolyzate phase
BT  - Proceedings of the 2015 International Conference on Materials, Environmental and Biological Engineering
PB  - Atlantis Press
SP  - 1047
EP  - 1050
SN  - 2352-5401
UR  - https://doi.org/10.2991/mebe-15.2015.234
DO  - https://doi.org/10.2991/mebe-15.2015.234
ID  - Ding2015/04
ER  -