Proceedings of the 2014 International Conference on Mechatronics, Electronic, Industrial and Control Engineering

Synthesis of a Novel Mono-(6-N- allylamino-6-deoxy)- -cyclodextrin Functional Monomer

Authors
Guolin Chen, Feng Feng, Min Liao, Yujian Liu, Ling Tang, Zhigang Xu, Zhimin Liu
Corresponding Author
Guolin Chen
Available Online November 2014.
DOI
https://doi.org/10.2991/meic-14.2014.238How to use a DOI?
Keywords
Mono-(6-N-allylamino-6-deoxy)-beta-cyclodextrin; Mono-(6-p-toluenesulfonyl)-beta-cyclodextrin;beta-Cyclodextrin; Allylamine; Functional monomer
Abstract

b-cyclodextrin (b-CD) is a kind of cyclic oligosaccharide with a unit of D-glucopyranose. It shows good molecular recognition ability for its unique physical and chemical properties and suitable cavity structure. It also is an important supermolecule. It is easy to be derived to get a variety of functional monomers which could be used for chromatographic solid phases and molecularly imprinted polymers. A novel mono-(6-N-allylamino-6-deoxy)-b-CD was synthesized by using mono-(6-p-toluenesulfonyl)- -cyclodextrin (6-OTs-ß-CD) and allylamine as reactants in the solvent of allylamine. The reaction conditions, such as reaction temperature, molar ratio of reactants and reaction time, were optimized. And the yield of 83.9% could be obtained based on the optimized conditions. The product was characterized by FT-IR, MS and 1HNMR. The characterization results further confirmed that the target product of mono-(6-N-allylamino-6-deoxy)-b-CD was successfully synthesized. The product was a novel functional monomer. It could be used for the preparation of polymers for further adsorption study.

Copyright
© 2014, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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Volume Title
Proceedings of the 2014 International Conference on Mechatronics, Electronic, Industrial and Control Engineering
Series
Advances in Engineering Research
Publication Date
November 2014
ISBN
978-94-62520-42-4
ISSN
2352-5401
DOI
https://doi.org/10.2991/meic-14.2014.238How to use a DOI?
Copyright
© 2014, the Authors. Published by Atlantis Press.
Open Access
This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

Cite this article

TY  - CONF
AU  - Guolin Chen
AU  - Feng Feng
AU  - Min Liao
AU  - Yujian Liu
AU  - Ling Tang
AU  - Zhigang Xu
AU  - Zhimin Liu
PY  - 2014/11
DA  - 2014/11
TI  - Synthesis of a Novel Mono-(6-N- allylamino-6-deoxy)- -cyclodextrin Functional Monomer
BT  - Proceedings of the 2014 International Conference on Mechatronics, Electronic, Industrial and Control Engineering
PB  - Atlantis Press
SP  - 1069
EP  - 1072
SN  - 2352-5401
UR  - https://doi.org/10.2991/meic-14.2014.238
DO  - https://doi.org/10.2991/meic-14.2014.238
ID  - Chen2014/11
ER  -