Synthesis of a Novel Mono-(6-N- allylamino-6-deoxy)- -cyclodextrin Functional Monomer
- 10.2991/meic-14.2014.238How to use a DOI?
- Mono-(6-N-allylamino-6-deoxy)-beta-cyclodextrin; Mono-(6-p-toluenesulfonyl)-beta-cyclodextrin;beta-Cyclodextrin; Allylamine; Functional monomer
b-cyclodextrin (b-CD) is a kind of cyclic oligosaccharide with a unit of D-glucopyranose. It shows good molecular recognition ability for its unique physical and chemical properties and suitable cavity structure. It also is an important supermolecule. It is easy to be derived to get a variety of functional monomers which could be used for chromatographic solid phases and molecularly imprinted polymers. A novel mono-(6-N-allylamino-6-deoxy)-b-CD was synthesized by using mono-(6-p-toluenesulfonyl)- -cyclodextrin (6-OTs-ß-CD) and allylamine as reactants in the solvent of allylamine. The reaction conditions, such as reaction temperature, molar ratio of reactants and reaction time, were optimized. And the yield of 83.9% could be obtained based on the optimized conditions. The product was characterized by FT-IR, MS and 1HNMR. The characterization results further confirmed that the target product of mono-(6-N-allylamino-6-deoxy)-b-CD was successfully synthesized. The product was a novel functional monomer. It could be used for the preparation of polymers for further adsorption study.
- © 2014, the Authors. Published by Atlantis Press.
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- This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Cite this article
TY - CONF AU - Guolin Chen AU - Feng Feng AU - Min Liao AU - Yujian Liu AU - Ling Tang AU - Zhigang Xu AU - Zhimin Liu PY - 2014/11 DA - 2014/11 TI - Synthesis of a Novel Mono-(6-N- allylamino-6-deoxy)- -cyclodextrin Functional Monomer BT - Proceedings of the 2014 International Conference on Mechatronics, Electronic, Industrial and Control Engineering PB - Atlantis Press SP - 1069 EP - 1072 SN - 2352-5401 UR - https://doi.org/10.2991/meic-14.2014.238 DO - 10.2991/meic-14.2014.238 ID - Chen2014/11 ER -