Study on Crystal Structure and Thermal Behavior of Sodium Tetrazolate and Sodium 5-Chlorotetrazolate
- https://doi.org/10.2991/icaemt-15.2015.104How to use a DOI?
- Energetic material, Coordination complex, Sodium 5-Chlorotetrazolate, Crystal structure, Kinetic parameter
Sodium tetrazolate and sodium 5-chlorotetrazolate crystals obtained by recrystallization centred on sodium ion, and the sodium ion was coordinated by tetrazolate rings and crystal water; the packing arrangements of sodium tetrazolate and sodium 5-chlorotetrazolate were rhombus structure which lead to highest thermostability and intersecting channel structure viewed along b axis, respectively; there was a gap between molecules and larger space viewed along a axis of sodium 5-chlorotetrazolate crystal drawing which can coordinate with nitrogen-rich groups and metal ion. The results of thermodynamics calculation indicated that the activation energy of sodium tetrazolate was about 200 kJ•mol-1, sodium 5-chlorotetrazolate was 260-270 kJ•mol-1 which was higher than sodium tetrazolate, however, the decomposition temperature of sodium 5-chlorotetrazolate (241 °C) was lower than sodium tetrazolate (320 °C) which can be explained that the pre-exponential factor (lgA) of sodium 5-chlorotetrazolate (27.8) was greater than that of sodium tetrazolate (18.2), in other words, sodium 5-chlorotetrazolate had more active sites.
- © 2015, the Authors. Published by Atlantis Press.
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- This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Cite this article
TY - CONF AU - Xiaojun Wang AU - Jiping Liu AU - Xiaolu Bi AU - Hongcheng Li AU - Wei Zhao AU - Dong Wang PY - 2015/08 DA - 2015/08 TI - Study on Crystal Structure and Thermal Behavior of Sodium Tetrazolate and Sodium 5-Chlorotetrazolate BT - Proceedings of the 2015 International Conference on Advanced Engineering Materials and Technology PB - Atlantis Press SP - 543 EP - 548 SN - 2352-5401 UR - https://doi.org/10.2991/icaemt-15.2015.104 DO - https://doi.org/10.2991/icaemt-15.2015.104 ID - Wang2015/08 ER -