Proceedings of the 2015 International Conference on Materials Chemistry and Environmental Protection (meep-15)

Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(3-methyl)-phenyl-3-thienyl] Perfluorocyclopentene

Authors
J.J. Liu, H.L. Liu, S.Z. Pu
Corresponding Author
J.J. Liu
Available Online March 2016.
DOI
https://doi.org/10.2991/meep-15.2016.21How to use a DOI?
Keywords
diarylethene; photochromism; pyrimidine; fluorescence
Abstract
A novel photochromic diarylethene bearing a pyrimidine moiety, 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2- methyl-5-(3-methyl)-3-thienyl]perfluorocyclopentene has been synthesized. Its properties, including photochromic and fluorescent behaviors, have been investigated. The compound exhibited remarkable photochromism, changing from colorless to red after irradiation with UV light in solution. The cyclization/cycloreversion process of the compound was determined to be the zeroth/first order reaction. The results indicated that the pyrimidine moiety played a very important role during the process of photoisomerization reactions.
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Proceedings
International Conference on Materials Chemistry and Environmental Protection 2015
Part of series
Advances in Physics Research
Publication Date
March 2016
ISBN
978-94-6252-169-8
ISSN
2352-541X
DOI
https://doi.org/10.2991/meep-15.2016.21How to use a DOI?
Open Access
This is an open access article distributed under the CC BY-NC license.

Cite this article

TY  - CONF
AU  - J.J. Liu
AU  - H.L. Liu
AU  - S.Z. Pu
PY  - 2016/03
DA  - 2016/03
TI  - Synthesis and Properties Study of 1-(2,4-dimethoxyl-5-pyrimidinyl)-2-[2-methyl-5-(3-methyl)-phenyl-3-thienyl] Perfluorocyclopentene
BT  - International Conference on Materials Chemistry and Environmental Protection 2015
PB  - Atlantis Press
SN  - 2352-541X
UR  - https://doi.org/10.2991/meep-15.2016.21
DO  - https://doi.org/10.2991/meep-15.2016.21
ID  - Liu2016/03
ER  -