A Gadolinium(III) complex based on Nitronyl nitroxide ligand exhibiting magnetic relaxation process

DOI

10.2991/mseee-17.2017.79How to use a DOI?

Keywords

Lanthanides, Crystal structure, Single-ion magnet, Slow magnetic relaxation.

Abstract

Reaction of the nitronyl nitroxide radical NIT-CH3 with Gd(hfac)3 affords a one-dimensional lanthanide–nitronyl nitroxide compound: [Gd (hfac)3 (NIT-CH3)]n (1) Single crystal X-ray crystallographic analysis reveals that this compound is one-dimensional chain built up by Gd(hfac)3 units bridged by radicals through their NO groups. DC magnetic susceptibilities indicate that Gd complex paramagnetic above 2.0 K

Copyright

© 2017, the Authors. Published by Atlantis Press.

Open Access

This is an open access article distributed under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).

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TY  - CONF
AU  - Peng Hu
AU  - Fengping Xiao
PY  - 2017/08
DA  - 2017/08
TI  - A Gadolinium(III) complex based on Nitronyl nitroxide ligand exhibiting magnetic relaxation process
BT  - Proceedings of the 2017 International Conference on Material Science, Energy and Environmental Engineering (MSEEE 2017)
PB  - Atlantis Press
SP  - 431
EP  - 433
SN  - 2352-5401
UR  - https://doi.org/10.2991/mseee-17.2017.79
DO  - 10.2991/mseee-17.2017.79
ID  - Hu2017/08
ER  -